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    從電化學阻抗曲線分析雙電層電容Cdl
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    Introduction
    With the introduction of a constant phase element (CPE) as a replacement for the capacity in
    EIS measurements, most of the experimentally obtained results could be fitted by
    commercially available software (Gamry, Scribner, Solartron, etc.). Much better fit results
    were obtained with CPE in comparison with the fit results obtained by using pure capacity,
    represented by parallel plate condenser. Taking into account that the CPE defines
    inhomogeneity of the surface in the electrochemical EIS experiments and inhomogeneity of
    the charge distribution in solid state EIS measurements, it is reasonable to expect that better
    fit for real systems is obtained by using CPE. The main problem in the use of commercially
    available software with CPE is the fact that the capacity, obtained by fitting procedure, does
    not have the dimension of capacity, i.e., F cm-2, or Ω-1cm-2 s, but its dimension is given
    in Ω-1 cm-2 sa, where a is the exponent in the equation for the CPE [1] ( ZCPE = Zdl(jω)-a ).
    This problem has been discussed in few papers [2-4] and recently Hsu and Mansfeld [5]
    developed the equation for correction of capacity to its real value, in the case of parallel
    connection of CPE and R, by using equation (1)......

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